DONOR-C安全技术说明书英文版2

Material: 60003427

SILANE CHM-DIMETHOXY

Version: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.2009

Commercial product name:

SILANE CHM-DIMETHOXY Industrial.

Intermediate chemical

1.1 Name of substance/preparation

1.2 Use of substance / preparation:

1.3 Company name

Manufacturer: Street/POB-No.:

State/postal code/city: Telephone: Telefax: Distributor:

Street/POB-No.:

State/postal code/city: Telephone: Telefax:

Wacker Chemie AG Hanns-Seidel-Platz 4 D 81737 München +498962790 +[1**********]0

Wacker Chemie AG

Care of Wacker Chemicals Australia Pty Ltd Unit 1 / 35 Dunlop Road Mulgrave, Victoria 3170 +61 3 9541 8900 +61 3 9541 8989

+61 3 9541 89001800 033 111

1.4 Emergency telephone number

Emergency information:

Emergency response service only (24h): Regulatory Compliance Manager

Orica Australia SH&E Shared Services

HAZARDOUS SUBSTANCE (according to the criteria of NOHSC). DANGEROUS GOOD (according to the ADG Code).

2.1 Classification:

2.2 Further hazards to man and environment: Inhalation of aerosol spray may damage health. Product hydrolyses under formation of methanol (CAS no. 67-56-1). Methanol is toxic if inhaled,

swallowed or comes into contact with the skin (T, R23/24/25), leads to irreversible damage if inhaled, comes into contact with the skin or is swallowed (T, 39/23/24/25) and is highly flammable (F, R11).

Composition/information on ingredients

3.1 Chemical characterization (substance):

3.2 Hazardous ingredients:

Cyclohexyldimethoxymethylsil

ane

38-51/53

Material: 60003427

SILANE CHM-DIMETHOXY

Version: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.2009

If the sum of ingredients is less than 100%, the material consists of further ingredients determined not to be hazardous or below their cut-off limits.

First-aid measures

4.1 General information: Take persons to a safe place. Observe self-protection for first aid.

4.2 After inhalation: Keep the patient calm. If unconscious place in stable sideways position. Protect against loss

of body heat. In cases of sickness seek medical advice (show label or SDS if possible).

4.3 After contact with the skin: Remove contaminated or soaked clothing. Immediately rinse with plenty of soap and water. In the

event of a visible skin change or other complaints, seek medical advice (show label or SDS where possible).

4.4 After contact with the eyes: Rinse immediately with plenty of water for 10-15 minutes. Seek medical advice in case of

continuous irritation.

4.5 After swallowing: If conscious, give several small portions of water to drink. Do not induce vomiting. Seek

medical advice immediately and clearly identify substance.

4.6 Advice for the doctor: In case of contact with water material splits off (also in gastrointestinal tract) methanol in

larger amounts; therefore consider poisoning on methanol and also observe known period of latency of several days!

5.1 Suitable extinguishing media: water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .

5.2 Extinguishing media which must not be used for safety reasons: water spray , water jet .

5.3 Special exposure hazards arising from the substance or preparation itself, combustion products,

resulting gases:

-

5.4 Special protective equipment for fire fighting: Use respiratory protection independent of recirculated air.

6.1 Personal precautions: Wear personal protection equipment (see section 8). Keep unprotected persons away. Avoid

contact with eyes and skin. Avoid inhaling mists and vapours. If material is released indicate risk of slipping.

6.2 Environmental precautions: Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid

that runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked containers.

6.3 Methods for cleaning up: Do not flush away with water. For small amounts: Absorb with a liquid binding material such as

diatomaceous earth and dispose of according to local/state/federal regulations. Contain larger amounts and pump up into suitable containers. Clean any slippery coating that remains using a detergent / soap solution or another biodegradable cleaner. Exhaust vapours.

Material: 60003427

SILANE CHM-DIMETHOXY

Version: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.2009

6.4 Further information: Eliminate all sources of ignition.

Precautions for safe handling:

Ensure adequate ventilation. Keep away from incompatible substances in accordance with section 10.2. Spilled substance increases risk of slipping.

Precautions against fire and explosion:

Product can separate methanol. Flammable vapors may accumulate and form explosive mixtures with air in containers, process vessels, including partial, empty and uncleaned containers and vessels, or other enclosed spaces. Keep away from sources of ignition and do not smoke. Take precautionary measures against electrostatic charging. Cool endangered containers with water. Conditions for storage rooms and vessels:

Make sure there is no possibility of entering the ground.

7.1 Handling

7.2 Storage

Advice for storage of incompatible materials:

not applicable

Further information for storage:

Protect against moisture. Store in original container only. Keep container tightly closed and store in a cool, well ventilated place.

7.3 Regulations and standards (Australia): Store in accordance with Dangerous Goods (Storage & Handling) Regulations and AS/NZS 4681 The

Storage and Handling of Class 9 (miscellaneous) Dangerous Goods and Articles.Also classified as a C1 Combustible Liquid which should be stored in accordance with AS 1940 Storage & Handling of Flammable & Combustible Liquids.

Maximum airborne concentrations at the workplace: 67-56-1 OEL -

Methanol (CAS no. 67-56-1): Refer to Technical Rules for Hazardous Substances "TRGS 900" for more details on the German AGW.

8.1 Exposure limits

8.2 Exposure limited and controlled

8.2.1 Exposure in the work place limited and controlled

General protection and hygiene measures:

Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling.

Personal protection equipment Respiratory protection:

In case of long or strong exposure: gas mask filter ABEK .

Hand protection:

Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use. Eye protection:

tight fitting protective goggles . Skin protection:

protective clothing .

Material: 60003427

SILANE CHM-DIMETHOXY

Version: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.2009

8.2.2 Exposure to the environment limited and controlled: Prevent material from entering surface waters, drains or sewers and soil.

8.2.3 Specific notes (Australia): Select and use respirators in accordance with AS1715/1716.

8.3 Further information for system design and engineering measures: Observe information in section 7.

O 9.1 General information Physical state / form................: liquid

Colour...............................: colourless Odour................................: slight

9.2 Important information about the protection of health, safety and the environment Melting point / melting range........:

Density..............................: 0.94 g/cm³ at 25 °C, at 1013 hPa Water solubility / miscibility.......: 0.28 g/l at 20 °C Solubility in organic solvent........: totally miscible with common organic

solvents

pH-Value.............................: not applicable Viscosity (dynamic)..................: 1.6 mPa.s at 25 °C Viscosity (kinematic)................: 1.7 mm²/s at 25 °C

Method

(67/548/EEC):

(DIN 51758) (ISO 9038) (DIN 51794)

(DIN 51757)

(DIN 51562)

9.3 ther information Re 9.2 solubility in water: Hydrolytic decomposition occurs. Explosion limits for

released methanol: 5.5 - 44%(V). Re 9.2 pH Value: Product displays neutral reaction.

Thermal decomposition................: No decomposition when used according to

regulations.

10.0 General information: If stored and handled in accordance with standard industrial practices no hazardous reactions

are known.

10.1 Conditions to avoid: moisture

10.2 Materials to avoid: Reacts with: water , basic substances and acids . Reaction causes the formation of: methanol .

10.3 Hazardous decomposition products: If stored and handled in accordance with standard industrial practices and local regulations

where applicable: none known . By hydrolysis: methanol .

Material: 60003427

SILANE CHM-DIMETHOXY

Version: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.2009

11.0 General information: Note indications of danger and safety advice (R- and S-phrases) in section 15.

11.1 Toxicological tests

Acute toxicity (LD50/LC50-values relevant to classification): oral 4071 mg/kg dermal > 2000 mg/kg by inhalation > 5.03 mg/l/4h (spray / dust) Specific symptoms in animal test:

Acute inhalation: No mortality with the given dose. Primary irritation: Sensitization:

Kligmann

Further information:

-

Subacute to chronic toxicity: rat Repeated Dose 28-day

Oral Toxicity Study in Rodents

NOAEL

Reference points for mutagenic potential: Test system

Genetic Toxicology: Rodent Dominant Lethal Test Mammalian Erythrocyte Micronucleus Test Bacterial Reverse Mutation Test

11.2 Experience with man: -

11.3 Further toxicological information: Product(s) of hydrolysis: Attention! Product may hydrolyse in gastro-intestinal tract and

produce methanol. According to literature methanol (67-56-1) irritates mucuous membranes, has skin drying and narcotic effects up to coma or death. Absorption by the skin is possible. Possibility of damage to heart, kidneys, liver and optic nerves (blindness) over a period of time.

12.1 Ecotoxicity

mykiss)

Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

12.2 Mobility -

Material: 60003427

SILANE CHM-DIMETHOXY

Version: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.2009

12.3 Persistence and degradability

Biodegradation:

Bottle Test

Hydrolysis: Method

Hydrolysis as a function of pH.

Further information:

Contact with water liberates: Methanol and silanol- and/or siloxanol-compounds .

12.4 Bio-accumulation potential -

12.5 Other harmful effects

-

12.6 Additional information

General information:

Prevent material from entering surface waters, drains or sewers and soil.

13.1 Material

Recommendation:

Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations.

Recommendation:

Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local/state/federal regulations.

13.2 Uncleaned packaging

14.1 Land transport ADG Code (road and rail): Valuation....................: Hazardous product Class........................: 9 Packaging Group..............: III UN no. ......................: 3082 Proper Shipping Name.........: Environmentally hazardous substance, liquid, n.o.s. Technical name...............: (Cyclohexyldimethoxymethylsilane) HazChem Further information..........: Environmentally Hazardous Substances meeting the descriptions of

UN 3077 or UN 3082 are not subject to the ADG Code when

transported by road or rail in (a) packagings; (b) IBCs; or (c) any other receptacle not exceeding 500 kg(L).

14.2 Transport by sea IMDG-Code

Valuation....................: Hazardous product Class........................: 9 Packaging Group..............: III UN no. ......................: 3082 Proper Shipping Name.........: Environmentally hazardous substance, liquid, n.o.s. Technical name...............: (Cyclohexyldimethoxymethylsilane) Marine Pollutant.............: yes

14.3 Air transport ICAO-TI/IATA-DGR

Valuation....................: Hazardous product Class........................: 9

Material: 60003427

SILANE CHM-DIMETHOXY

Version: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.2009

Packaging Group..............: III UN no. ......................: 3082 Proper Shipping Name.........: Environmentally hazardous substance, liquid, n.o.s. Technical name...............: (Cyclohexyldimethoxymethylsilane)

15.1 Warning Label (EC)

Xi N

Irritant

Dangerous for the environment

environment.

Avoid contact with skin.

Avoid release to the environment. Refer to special instructions / safety data sheets. 402-140-1

EC-No.:

Hazard ingredients (labelling EC):

15.2 National regulations:

15.2.1 Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) Australia:

Poisons Schedule number:

No Poisons Schedule number allocated.

15.3 Other international regulations

Details of international registration status

Listed on or in accordance with the following inventories: IECSC - China

PICCS - Philippines ENCS - Japan ELINCS - Europe ECL - Korea DSL - Canada AICS - Australia TSCA - USA

16.1 Material

The above information describes exclusively the safety requirements of the product(s) and is based on our present-day knowledge. It does not represent a guarantee for the properties of the product(s) described in terms of the legal warranty regulations.Properties of the product are to be found in the respective product leaflet.

16.2 Further information:

Vertical lines in the left-hand margin indicate changes compared with the previous version. This version supersedes all previous versions.

Material: 60003427

SILANE CHM-DIMETHOXY

Version: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.2009

16.3 Glossary of Terms:

CAS No. - Chemical Abstracts Service Registry Number UN No. - United Nations Dangerous Goods Number

ADG Code - Australian Dangerous Goods Code for the Transport of Dangerous Goods by Road & Rail IMDG Code - International Maritime Dangerous Goods Code

IATA Regs - International Air Transport Association (IATA) Dangerous Goods Regulations

NOHSC - Australian National Occupational Health and Safety Commission (Note: NOHSC documents are now published by the ASCC)

ASCC - Australian Safety & Compensation Council OEL - Occupational exposure limit in Great Britain AGW - Occupational exposure limit in Germany

ES_AU - Occupational exposure limit in Australia

- End of Safety Data Sheet -