N-乙烯基己内酰胺
N-乙烯基己内酰胺
基本信息安全数据图谱信息
物理化学性质
2235-00-9 结构式
知名试剂公司产品信息供应商
N-乙烯基己内酰胺价格(试剂级)
基本信息
【中文】
N-乙烯基己内酰胺
【英文名称】
1-ethenylazepan-2-one
1-Ethenylhexahydro-2H-azepin-2-one 1-vinylhexahydro-2h-azepin-2-one N-VINYLCAPROLACTAM
N-VINYL-EPSILON-CAPROLACTAM VINYLCAPROLACTAM
1-ethenylhexahydro-2h-azepin-2-on 2H-Azepin-2-one, 1-ethenylhexahydro- n-vinyl-
N-VINYL-E-CAPROLACTAM
1-Ethenyl-2,3,4,5,6,7-hexahydro-1H-azepin-2-one 1-Vinyl-4,5,6,7-tetrahydro-1H-azepine-2(3H)-one 1-Vinylhexahydro-1H-azepine-2-one
【CAS】
2235-00-9
【中文名称】
N-乙烯基己内酰胺
1-乙烯基六氢-2H-Y庚因-2-酮 乙烯基己内酰胺 N-乙烯己内酰胺
【EINECS 编号】
218-787-6
【分子式】
C8H13NO
【MDL 编号】
MFCD00080693
【分子量】
139.19
【MOL 文件】
2235-00-9.mol
物理化学性质
【熔点 】
35-38 °C (dec.)(lit.)
【沸点 】
128 °C21 mm Hg(lit.)
【密度 】
1.029 g/mL at 25 °C(lit.)
【折射率 】
1.
【闪点 】
214 °F
安全数据
【危险品标志 】
Xn
【危险类别码 】
R22-R41
Risk Phrases
Indication of Particular Risks
R1: Explosive when dry
2: Risk of explosion by shock, friction, fire or other sources of ignition
3: Extreme risk of explosion by shock, friction, fire or other sources of ignition
4: Forms very sensitive explosive metallic compounds 5: Heating may cause an explosion 6: Explosive with or without contact with air 7: May cause fire
8: Contact with combustible material may cause fire 9: Explosive when mixed with combustible material 10: Flammable 11: Highly Flammable 12: Extremely Flammable 14: Reacts violently with water
15: Contact with water liberates extremely flammable
gases
16: Explosive when mixed with oxidizing substances 17: Spontaneously flammable in air
18: In use may form flammable/explosive vapor-air
mixture
19: May form explosive peroxides 20: Harmful by inhalation 21: Harmful in contact with skin 22: Harmful if swallowed 23: Toxic by inhalation 24: Toxic in contact with skin 25: Toxic if swallowed 26: Very Toxic by inhalation 27: Very Toxic in contact with skin 28: Very Toxic if swallowed 29: Contact with water liberates toxic gas 30: Can become highly flammable in use 31: Contact with acids liberates toxic gas
35: Causes severe burns 36: Irritating to the eyes 37: Irritating to the respiratory system 38: Irritating to the skin
39: Danger of very serious irreversible effects 40: Limited evidence of a carcinogenic effect 41: Risk of serious damage to eyes 42: May cause sensitization by inhalation 43: May cause sensitization by skin contact 44: Risk of explosion if heated under confineme 45: May cause cancer
46: May cause heritable genetic damage 48: Danger of serious damage to health by
exposure
49: May cause cancer by inhalation 50: Very Toxic to aquatic organisms 51: Toxic to aquatic organisms 52: Harmful to aquatic organisms 53: May cause long-term adverse effects in environment 54: Toxic to flora 55: Toxic to fauna 56: Toxic to soil organisms 57: Toxic to bees
58: May cause long-term adverse effects
environment
59: Dangerous for the ozone layer 60: May impair fertility
61: May cause harm to the unborn child 62: Possible risk of impaired fertility 63: Possible risk of harm to the unborn child 64: May cause harm to breast-fed babies 65: Harmful: May cause lung damage if swallow 66: Repeated exposure may cause skin th
dr
32: Contact with acids liberates very toxic gas 33: Danger of cumulative effects 34: Causes burns
cracking
67: Vapors may cause drowsiness and dizziness 68: Possible risk of irreversible effects
Risk Phrases
Combination of Particular Risks
14/15: Reacts violently with water, liberating extremely
flammable gases
15/29: Contact with water liberates toxic, extremely
flammable gas
20/21: Harmful by inhalation and in contact with skin 20/21/22: Harmful by inhalation, in contact with skin and if
swallowed
20/22: Harmful by inhalation and if swallowed 21/22: Harmful in contact with skin and if swallowed 23/24: Toxic by inhalation and in contact with skin 23/24/25: Toxic by inhalation, in contact with skin and if
swallowed
48/20: Harmful: danger of serious damag
prolonged exposure through inhalatio
48/20/21: Harmful: danger of serious damag
prolonged exposure through inhacontact with skin
48/20/21/22: Harmful: danger of serious damag
prolonged exposure through inhacontact with skin and if swallowed 48/20/22: Harmful: danger of serious damag
prolonged exposure through inhaswallowed
48/21: Harmful: danger of serious damag
prolonged exposure in contact with s
48/21/22: Harmful: danger of serious damag
prolonged exposure in contact wiswallowed
48/22: Harmful: danger of serious damag
prolonged exposure if swallowed 48/23: Toxic: danger of serious damage
prolonged exposure through inhalatio
48/23/24: Toxic: danger of serious damage
prolonged exposure through inhacontact with skin
48/23/24/25: Toxic: danger of serious damage
prolonged exposure through inhalawith skin and if swallowed 48/23/25: Toxic: danger of serious damage
prolonged exposure through inhaswallowed
48/24: Toxic: danger of serious damage
prolonged exposure in contact with s
23/25: Toxic by inhalation and if swallowed 24/25: Toxic in contact with skin and if swallowed 26/27: Very Toxic by inhalation and in contact with skin 26/27/28: Very Toxic by inhalation, in contact with skin and if
swallowed
26/28: Very Toxic by inhalation and if swallowed 27/28: Very Toxic in contact with skin and if swallowed 36/37: Irritating to eyes and respiratory system 36/37/38: Irritating to eyes, respiratory system and skin 36/38: Irritating to eyes and skin 37/38: Irritating to respiratory system and skin 39/23: Toxic: danger of very serious irreversible effects
through inhalation
39/23/24: Toxic: danger of very serious irreversible effects
through inhalation in contact with skin
39/23/24/25: Toxic: danger of very serious irreversible effects
through inhalation, in contact with skin and if swallowed
39/23/25: Toxic: danger of very serious irreversible effects
through inhalation and if swallowed 39/24: Toxic: danger of very serious irreversible effects in
contact with skin
39/24/25: Toxic: danger of very serious irreversible effects in
contact with skin and if swallowed
39/25: Toxic: danger of very serious irreversible effects if
swallowed
39/26: Very Toxic: danger of very serious irreversible
effects through inhalation
39/26/27: Very Toxic: danger of very serious irreversible
effects through inhalation and in contact with skin
39/26/27/28: Very Toxic: danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed
39/26/28: Very Toxic: danger of very serious irreversible
effects through inhalation and if swallowed 39/27: Very Toxic: danger of very serious irreversible
effects in contact with skin
Very Toxic: danger of very serious irreversible 39/27/28:
effects in contact with skin and if swallowed 39/28: Very Toxic: danger of very serious irreversible
effects if swallowed
42/43: May cause sensitization by inhalation and skin
contact
48/24/25: Toxic: danger of serious damage to health by
prolonged exposure in contact with skin and if swallowed
48/25: Toxic: danger of serious damage to health by
prolonged exposure if swallowed
50/53: Very Toxic to aquatic organisms, may cause
long-term
adverse
effects
in
the
aquatic
environment
51/53: Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment 52/53: Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment 68/20: Harmful: possible risk of irreversible effects through
inhalation
68/20/21: Harmful: possible risk of irreversible effects through
inhalation and in contact with skin
68/20/21/22: Harmful: possible risk of irreversible effects through
inhalation, in contact with skin and if swallowed 68/20/22: Harmful: possible risk of irreversible effects through
inhalation and if swallowed
68/22: Harmful: possible risk of irreversible effects if
swallowed
68/21: Harmful: possible risk of irreversible effects in
contact with skin
68/21/22: Harmful: possible risk of irreversible effects in
contact with skin and if swallowed
68/22: Harmful: possible risk of irreversible effects if
swallowed
Safety Phrases
Indication of Safety Precautions
S1: Keep locked up
2: Keep out of the reach of children 3: Keep in a cool place 4: Keep away from living quarters
5: Keep contents under ... (appropriate liquid to be
37: Wear suitable gloves
38: In case of insufficient ventilation, we
respiratory equipment 39: Wear eye/face protection
40: To clean the floor and all objects contamin
specified by the manufacturer)
6: Keep under ... (inert gas to be specified by the manufacturer)
7: Keep container tightly closed 8: Keep container dry
9: Keep container in a well-ventilated place 12: Do not keep the container sealed
13: Keep away from food, drink and animal feeding stuffs 14: Keep away from ... (incompatible materials to be
indicated by the manufacturer) 15: Keep away from heat
16: Keep away from sources of ignition - No smoking 17: Keep away from combustible material 18: Handle and open container with care 20: When using, do not eat or drink 21: When using, do not smoke 22: Do not breathe dust
23: Do not breathe gas/fumes/vapor/spray (appropriate
wording to be specified by the manufacturer) 24: Avoid contact with skin 25: Avoid contact with eyes
26: In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice 27: Take off immediately all contaminated clothing 28: After contact with skin, wash immediately with plenty
of ... (to be specified by the manufacturer) 29: Do not empty into drains 30: Never add water to this product
33: Take precautionary measures against static discharges 35: This material and its container must be disposed of in a safe way
36: Wear suitable protective clothing
material use ... (to be specified by the manufacturer) 41: In case of fire and/or explosion do not breathe fumes 42: During fumigation/spraying wear suitable respiratory
equipment (appropriate wording to be specified) 43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 46: If swallowed, seek medical advice immediately and
show this container or label
47: Keep at temperature not exceeding ... E C (to be
specified by the manufacturer)
48: Keep wetted with ... (appropriate material to be
specified by the manufacturer) 49: Keep only in the original container
50: Do not mix with ... (to be specified by the manufacturer) 51: Use only in well-ventilated areas
52: Not recommended for interior use on large surface
areas
53: Avoid exposure - obtain special instruction before use 56: Dispose of this material and its container to hazardous or special waste collection point
57: Use appropriate container to avoid environmental
contamination
59: Refer to manufacturer/supplier for information on
recovery/recycling
60: This material and/or its container must be disposed of
as hazardous waste
61: Avoid release to the environment. Refer to special
instructions safety data sheet
62: If swallowed, do not induce vomiting: seek medical
advice immediately and show this container or label 63: In case of accident by inhalation, remove casualty to
fresh air and keep at rest
64: If swallowed, rinse mouth with water (only if the person is conscious)
Safety Phrases
Combination of Safety Precautions
1/2: Keep locked up and out of the reach of children 3/7: Keep container tightly closed in a cool place 3/9/14: Keep in a cool well-ventilated place away from ...
(incompatible
materials
to
be
indicated
by
manufacturer)
3/9/14/49: Keep only in the original container in a cool
well-ventilated place away from ... (incompatible materials to be indicated by manufacturer) 3/9/49: Keep only in the original container in a cool
well-ventilated place
3/14: Keep in a cool place away from ... (incompatible
materials to be indicated by the manufacturer) 7/8: Keep container tightly closed and dry
7/9: Keep container tightly closed and in a well-ventilated place
7/47: Keep container tightly closed and at a temperature not
exceeding ... °C (to be specified by manufacturer) 20/21: When using, do not eat, drink or smoke
24/25: Avoid contact with skin and eyes
27/28: After contact with skin, take off immediately all
contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer) 29/35: Do not empty into drains, dispose of this container and
it's material in a safe way
29/56: Do not empty into drains, dispose of this material and
its container to hazardous or special waste-collection point
36/37: Wear suitable protective clothing and gloves 36/37/39: Wear suitable protective clothing, gloves and eye/face
protection
36/39: Wear suitable protective clothing and eye/face
protection
37/39: Wear suitable gloves and eye/face protection 47/49: Keep only in the original container at temperature not
exceeding ... °C (to be specified by manufacturer)
FLUKA BRAND F CODES
F 1 Sensitive to air and F 5 Dry material may explode. humidity.
F 6 Reacts with acids.
F 24 Spontaneously flammable with alcohol. F 25 Keep under CO.
F 26 Before distillation test for absence of peroxides.
F 27 Cool before opening.
F 28 May become cloudy (Polyformaldehyde). F 29 Spontaneously flammable when dry. F 30 Sediment unavoidable. F 31 Do not puncture.
F 32 Avoid contact with heavy metal salts especially iron salts. F 33 Causes fall in blood pressure. F 34 Sensitive to CO2.
F 2 Sensitive to air and CO2. F 7 Keep under CO2. F 3 Hygroscopic.
F 4 Do not heat over …°C. 1 = 10 °C 2 = 20 °C
F 8 Photosensitive. F 9 Keep under nitrogen. F 10 Keep under argon. F 11 Keep under inert gas. F 12 Shake before use. F 13 Malodorous.
F 14 Carefully observe warning label. F 15 Limited shelf life. F 16 Decomposes easily.
F 17 May decompose by explosion.
3 = 30 °C 4 = 40 °C 5 = 50 °C 6 = 60 °C 7 = 70 °C 8 = 80 °C 9 = 90 °C 10 = 100 °C 11 = 110 °C
F 18 Must be handled by instructed people F 35 Narcotic effects. only.
F 19 Lachrymator.
F 36 Extremely sensitive to air.
12 = 120 °C 13 = 130 °C 14 = 140 °C 15 = 150 °C
F 20 Not to be swallowed. F 21 Sensitive to humidity. F 22 Keep dust-free in the dark. F 23 Sensitive to air.
PICTOGRAMS AND HAZARD CODES
F Highly Flammable
B Biohazard
F+
Extremely Flammable
O Oxidizing
C Corrosive
Xn
Harmful Xi Irritant
R Radioactive T Toxic T+ Very Toxic
E Explosive
N Dangerous for the environment
【安全说明 】
S26-S39
Safety Phrases
Indication of Safety Precautions
S1: Keep locked up
2: Keep out of the reach of children 3: Keep in a cool place 4: Keep away from living quarters
5: Keep contents under ... (appropriate liquid to be specified by the manufacturer)
6: Keep under ... (inert gas to be specified by the manufacturer)
7: Keep container tightly closed 8: Keep container dry
9: Keep container in a well-ventilated place 12: Do not keep the container sealed
13: Keep away from food, drink and animal feeding stuffs 14: Keep away from ... (incompatible materials to be
indicated by the manufacturer) 15: Keep away from heat
16: Keep away from sources of ignition - No smoking
37: Wear suitable gloves
38: In case of insufficient ventilation, wear
respiratory equipment 39: Wear eye/face protection
40: To clean the floor and all objects contaminate material use ... (to be specified by the manufac41: In case of fire and/or explosion do not breathe 42: During fumigation/spraying wear suitable re
equipment (appropriate wording to be specified43: In case of fire, use ... (indicate in the space th type of fire-fighting equipment. If water increrisk add - Never use water)
45: In case of accident or if you feel unwell, seek advice immediately (show label where possible46: If swallowed, seek medical advice immedia
show this container or label
47: Keep at temperature not exceeding ... E
17: Keep away from combustible material 18: Handle and open container with care 20: When using, do not eat or drink 21: When using, do not smoke 22: Do not breathe dust
23: Do not breathe gas/fumes/vapor/spray (appropriate
wording to be specified by the manufacturer) 24: Avoid contact with skin 25: Avoid contact with eyes
26: In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice 27: Take off immediately all contaminated clothing 28: After contact with skin, wash immediately with plenty
of ... (to be specified by the manufacturer) 29: Do not empty into drains 30: Never add water to this product
33: Take precautionary measures against static discharges 35: This material and its container must be disposed of in a safe way
36: Wear suitable protective clothing
specified by the manufacturer)
48: Keep wetted with ... (appropriate material to be
specified by the manufacturer) 49: Keep only in the original container
50: Do not mix with ... (to be specified by the manufacturer) 51: Use only in well-ventilated areas
52: Not recommended for interior use on large surface
areas
53: Avoid exposure - obtain special instruction before use 56: Dispose of this material and its container to hazardous or special waste collection point
57: Use appropriate container to avoid environmental
contamination
59: Refer to manufacturer/supplier for information on
recovery/recycling
60: This material and/or its container must be disposed of
as hazardous waste
61: Avoid release to the environment. Refer to special
instructions safety data sheet
62: If swallowed, do not induce vomiting: seek medical
advice immediately and show this container or label 63: In case of accident by inhalation, remove casualty to
fresh air and keep at rest
64: If swallowed, rinse mouth with water (only if the person is conscious)
Safety Phrases
Combination of Safety Precautions
1/2: Keep locked up and out of the reach of children 3/7: Keep container tightly closed in a cool place 3/9/14: Keep in a cool well-ventilated place away from ...
(incompatible
materials
to
be
indicated
by
manufacturer)
3/9/14/49: Keep only in the original container in a cool
well-ventilated place away from ... (incompatible materials to be indicated by manufacturer) 3/9/49: Keep only in the original container in a cool
24/25: Avoid contact with skin and eyes 27/28: After contact with skin, take off immed
contaminated clothing and wash imediately wof.... (to be specified by the manufacturer) 29/35: Do not empty into drains, dispose of this cont
it's material in a safe way
29/56: Do not empty into drains, dispose of this ma
its container to hazardous or special waste-point
well-ventilated place
3/14: Keep in a cool place away from ... (incompatible
materials to be indicated by the manufacturer)
7/8: Keep container tightly closed and dry
7/9: Keep container tightly closed and in a well-ventilated
place
7/47: Keep container tightly closed and at a temperature not
exceeding ... °C (to be specified by manufacturer) 36/37: Wear suitable protective clothing and gloves 36/37/39: Wear suitable protective clothing, gloves and eye/face protection 36/39: Wear suitable protective clothing and eye/face protection 37/39: Wear suitable gloves and eye/face protection 47/49: Keep only in the original container at temperature not
exceeding ... °C (to be specified by manufacturer) 20/21: When using, do not eat, drink or smoke
FLUKA BRAND F CODES
F 1 Sensitive to air and F 5 Dry material may explode. F 24 Spontaneously flammable with alcohol. humidity. F 6 Reacts with acids. F 25 Keep under CO.
F 2 Sensitive to air and CO2. F 7 Keep under CO2. F 26 Before distillation test for absence of F 3 Hygroscopic. F 8 Photosensitive. peroxides.
F 4 Do not heat over …°C. F 9 Keep under nitrogen. F 27 Cool before opening.
1 = 10 °C F 10 Keep under argon. F 28 May become cloudy (Polyformaldehyde). 2 = 20 °C F 11 Keep under inert gas. F 29 Spontaneously flammable when dry. 3 = 30 °C F 12 Shake before use. F 30 Sediment unavoidable.
4 = 40 °C F 13 Malodorous. F 31 Do not puncture.
5 = 50 °C F 14 Carefully observe warning label. F 32 Avoid contact with heavy metal salts 6 = 60 °C F 15 Limited shelf life. especially iron salts.
7 = 70 °C F 16 Decomposes easily. F 33 Causes fall in blood pressure.
8 = 80 °C F 17 May decompose by explosion. F 34 Sensitive to CO2.
9 = 90 °C F 18 Must be handled by instructed people F 35 Narcotic effects.
10 = 100 °C only. F 36 Extremely sensitive to air. 11 = 110 °C F 19 Lachrymator.
12 = 120 °C F 20 Not to be swallowed.
13 = 130 °C F 21 Sensitive to humidity.
14 = 140 °C F 22 Keep dust-free in the dark.
15 = 150 °C F 23 Sensitive to air.
PICTOGRAMS AND HAZARD CODES
F Highly Flammable
B Biohazard F+ Extremely O Oxidizing
Flammable C Corrosive Xn Harmful
Xi Irritant
R Radioactive
E Explosive
N Dangerous for the T Toxic
environment T+ Very Toxic
【WGK Germany 】
3
图谱信息 【图谱信息】
N-乙烯基己内酰胺(2235-00-9)核磁图(13CNMR) N-乙烯基己内酰胺(2235-00-9)红外图谱(IR1) N-乙烯基己内酰胺(2235-00-9)质谱(MS)
N-乙烯基己内酰胺(2235-00-9)核磁图(1HNMR) 知名试剂公司产品信息 【Alfa Aesar】
N-乙烯-ε-己内酰胺,99%
N-Vinyl-epsilon-caprolactam, 99%(2235-00-9)
【Sigma Aldrich】
2235-00-9(sigmaaldrich)
【TCI Shanghai】
N-乙烯基己内酰胺
N-Vinyl-epsilon-caprolactam,>98.0%(GC)(2235-00-9)