醛酮类化合物答案
醛酮类化合物答案
1、
H
C 2H 5O H
Cu,O C H 3C HO
H
C H 3C HC N
+
C H 3HC O O H
H C C H
Na N H H C C Na
H C
C C H 2C H 3
H 2
H 2C C HC H 2C H 3
C H 3C H 2C H 2Br
C
H 3C
H 2C
H 2C
H 2O
H C H 3C H 2C H 2O
H C H 3C H 2C H 2Mg Br
C H 3C
H 2C H 2C H 2O H
B r Et O
2
Mg Br
O
H 3O
O H
C u/OC HO
C HO H
H
O
H
O H
2、
(CH 3) 2C HC C H 2C H 3
O H
H 3)
2C HC HC
H 2C H
3
H 3C H
2C HO
(CH 3) 2C C HC
H 2C H
3
C H 3C O C H 3(CH 3)
2C HC
C H 2
C H 3
O H
(CH 3) 2C H 2C H 3
(CH 3) 2C
C HC H 2C H 3O 3
Zn/H 2O
C H 3C O C H C H 3C H 2C HO
/Na O H
C H 3C O O C HI 3
N H N H 2
N N H
(CH 3) 2C HC C H 2C H 3
3、
3
C
3
C
C
O
O
O
C O H
H
O
O H
O O H
H
3C
C
H 3C
O O
+
a
2+
O H
O
N H N H 2
O
O H Ca Cl
O H
3
N H N H
C
C H 3
O
Ca C 2H
4、
O
H
C 6H 5C HO
C C 6H 5C C H 3
O C H 3
O
C 6H 5
C H 2
C 6H 5
H C H 2
C 6H 5
O
C 6H
5
O
C H
3C
HO
C
H 3C
H
C HC
HO
H
3C
H 3C
C H 3I C H 3
C H 3
(CH C O ) O
C N
O
C H 3
O
C H 3C O O H
H 3
C 6H 5C
C H 3
C H 3
C H 3Mg I
O
O C HC C 6H 5
O
H C
C H
Na N H H C
C Na
BrC H C H C H H C
C C H 2C H 2C H 3
C H
3C H
2C H 2C C C H 2C H 2
C H
3
C
C H
C H 3
C
HO O H
H 3
C H
C HC HO
C H C H C H C H Li
O
C H 3C H C HC HC H 2C H 2C H 2C H 3
C H 3C H C HC HC H 2C H 2C H 2C H 3
H
K Mn O O H
C H C HO
3
+
O
C H 3C H
C HC HO
C H C H C H C H Li
H
C H 3C H
C HC HC H 2C H 2C H 2C H 3
BrC H 2C H 2C H 2C H 3
C 6H 5C HO
2C H 3C H 2C H 2C H 2Li
C H 3C HO
C HC HO
C 6H 5C H LiAl H C HC HO
C HC H 2O H
C 6H 5C H
C HC H
C 6H 5C H
C HC H
H O
O H
O
2BrC H 2C H 2C HO
BrC H 2C H 2C O
O
Br Mg C H 2C H 2C H
(CH 3) 2C HC H 2C H 2C O H
Na B H O
O H
(CH 3) 2C C H 2C H 2C HO
(CH 3) 2C C H 2C H 2C H 2O H
C H 3C H 2O H C H 3C H 2O H
O H
C H 3C H 2C C H 3
CrO C H 3C HO C H 3C H 2Br
2
C H 3C H 2Mg Br
H
C H 3C H 2C C H 3
O
H
H C C H H C C Na H C
C C H 2C H 3
C H 3
C H 2C C
H 3
B r
2Mg Br O H
2
C H 3C H 2C H 2C H 2C HO
O
O C
C H 2C H 2C H 3
O
C H 2C H 2C H 2C H 3
O H
Me
O
Me O
O Me O
AlCl 3
O H H
O H
O Me
Me
O H O H
O Me
O
H
H 3)
2C HC HC
H 3H
3) 2
C
C HC H
3
O
(CH
3) 2C
HC C H
3
C H 3
(CH 3) 2C HC
N O
O 2N
N H N H O H
2N O (CH 3) 2C HC HC H 3
(CH 3)
C HC C H 3
2S O 4
I 2Na O H
(CH 3) 2C
HC H
3(CH 3) 2C HC O O C HI 3
K
Mn O 4(C
H 3) 2
C
O
C H 3C O O H
8、
C 2H 5C 2H 5
C H 2C C H 3
C H 2C C H 3
C H H 2C O O H
H 22C H 3
H
C HC C H 2
9、
H
NO 2
NO 2
10、
C H 2
H 3C
H
C H 2
C H
3
C
3
C H 3
C H
2
C H 2C HO
H 3C
C H
C H 2C
O
C H 3
C H 2C O O H
3C
C H 2C
O
H 3C
C H
C H 2C O O H O
C H
2C O O H
H 3
C
C H
11、（1）
（
2）
H
H 3
Na B H 2
B H
H 32Ph
H O
H 32Ph
H
B H
（3）
H
C H
2C 6
H 5H 2C 6H 5
H
C H C H H
H 2C 6H 5H 2C 6H 5
H
C H C H O O H
O H
O
12、如果加成得到的醇只能得到一种C 7H 14O （D 3），则这种醇只可能是：
(CH 3) 3C
H C H 2C H 3
(CH 3C H 2) 3C
O
H
O H
它们的起始原料分别为A 1和A 2：
(CH 3) 3C
C HO
C H 3C H 2C
H 2C H
3
O
如果加成得到的醇，消去H 2O 后可能生成两种烯D 1、D 2，则它们可能是： C H 3C H 2C H
C H 2C H 2C H 2C H 3
C H 3C H 2C H
H C H 2C H 3
O H O H
C H 3
C H 3C H 2HC H 2C
H(CH 3)
2
O
H
它们的原料A 的结构可能是：
C H 3C H 2C H 2C H 2C HO
C H 3C H 2H
C HO
(CH
3) 2C
HC H 2C HO
C H
13
、
O
H
H O
H
O 2HO
Ag
O 2
O O H
I
14、
O
C H
O
C H 3HO H
C H 3C HO H Ph C HO
Ph C O O H
H 3HO C O Ph
C H C HO C O Ph C H 3C H
O 2N N N H
NO 2
H 3C
C H C H H C H O H
H 3C
HO
C H
C H 3
3
16、
O O H
H
C 2H 5
O
O
H
O
25H
O O O C 2H 5
C O O H
O H
C O O H
C 2H 5
C HO
O C 2H 5
O C 2H 5
O
H
C O O H
C O O H